We metallized OPP in Aluminium deposit chamber and I observed a variation in WVTR and OTR data with sampling position in the slit roll :
1. Why barrier seems to be better more deeper in the roll than near the surface ?
2. Where is the best location to take a representative sample : on the roll "out-of-chamber" or on the slit roll ?
Answer from CAB.
Polymer film as it is wound over rolls will build up a static charge that can attract airborne dust to the surface. This surface dust will get wound into the roll of film & will be carried through the vacuum coating process. Any dust that is coated may get moved after the coating process & leave behind an uncoated area called a pinhole or pin window.
Now every time the roll is unwound & rewound it can attract more dust each time. Thus from the film line the mill roll may be slit on the production machine into two to make two half mill rolls, each of these will then get unwound & rewound as they are converted from ½ mill rolls into whatever size rolls you are using. The areas of greatest contamination are likely to be the beginning & end of the rolls as the speed is accelerated & decelerated between stationary & full winding speed.
This extra contamination at the beginning & end of each roll will be cumulative. Each machine may well accelerate/decelerate the rolls at different rates & so there is likely to be a different length of higher contamination from each process.
Thus when it comes to deciding where to take measurements from it is worth going back to each process & estimating how much film is used before the speed is constant and how much film is used on the slow down to stop. This will give you some idea of the minimum distance you need to be into the roll before you might get consistent, representative results. It is also worth considering that surface contamination can be transferred from one surface to another & so these acceleration/deceleration distances are a minimum because it is possible that debris from these regions can be spread further into the roll during winding.
The greater the number of time the roll is wound the more surface contamination will be generated & the further into the roll it can have moved.
Thus, it is always better to minimise the amount a roll is handled (rewound) wherever possible.
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