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December 24, 2008

Converting School programme for first half 2009

Converting School programme for first half of 2009 

 

As you know AIMCAL offer a number of training courses each year. Here are those that have been selected to run in the first half of 2009.  If you wish to know further details of the course content please visit the AIMCAL website at www.aimcal.org where the details are available as well as a some details of each of the presenters.

 

 

March 10-11

Web Handling and Converting

Cleveland,Ohio  

Dr. David Roisum

 

March 12-13

Winding: Machines, Mechanics and Measurements

Cleveland,Ohio

Dr. David Roisum

 

March 10-11

Web Processing for Barrier

Brussels, Belgium

Dr. Charles Bishop

 

March 12-13

Vacuum Coating

Brussels, Belgium

Dr. Charles Bishop

 

April 21-22

Web Handling and Converting

Frankfurt, Germany

Dr. David Roisum

 

April 23-24

Winding: Machines, Mechanics and Measurements

Frankfurt, Germany

Dr. David Roisum

 

April 21-22

Solution Preparation and Mixing

Dallas, Texas

Dr. Kenneth McCarthy

 

April 23-24

Web Coating and Drying

Dallas, Texas

Dr. Edward Cohen

Dr. E.J. (Ted) Lightfoot

 

May 12-13

Web Handling and Converting

Chicago, Illinois

Dr. David Roisum

 

May 14-15

Winding: Machines, Mechanics and Measurements

Chicago, Illinois

Dr. David Roisum

 

May 19-20

Solution Preparation and Mixing

Brussels, Belgium

Dr. Kenneth McCarthy

 

May 21-22

Web Coating and Drying

Brussels, Belgium

Dr. Jonathan Summers

Dr. Harvey Thompson

December 22, 2008

Vacuum system design

            I recently had an e-mail discussion with Dr William (Bill) Llewellyn VP of AWA BV regarding system design which might give everyone something to think about.  

 

            It is interesting to note that in many essentials the basic aluminium metallizing systems are largely unchanged from those around decades ago.  Yes there have been improvements but it is interesting that a number of changes that could have made life easier for operators and reduced downtime have not been adopted. 

 

            For example here is the comment from Bill regarding the use of rotating source turrets.

‘On rotating sources, I was part of the team that initiated the concept with Galileo back in the late 1980s/early 1990s. The concept was to improve cycle efficiency by reducing the amount of time lost to source maintenance........and as a more cost effective alternative to air to air machines. The idea was to have one source in use within the machine, and a second source mounted on the same turntable that was being maintained outside the chamber.......boats and wire changed, wire feeds cleaned and checked, aluminium residues cleaned from source walls, etc, etc. When the source in use neared the end of its useful life, it was "unplugged" from the chamber, the turntable rotated through 180 degrees and the fresh source introduced with minimum time loss to production.

            The concept works well and was later copied by GVE for machines in the US. It does add cost, but there are gains in lower downtime for source maintenance, cleaning, etc. It also has the advantage that if a source is damaged, for example in a web break or shield leak, you have an effective "spare" to continue operations.’

 

 

            Another area that was developed and dropped was that of roll changing. As you will already know the polymer film makers regularly use flying splice technology. They can cut and remove completed rolls and re-attach the web to new cores without slowing down the film production.  In metallizing rolls have got larger and heavier and this makes them harder to handle and so automated handling has attractions.

 

Here is another comment from Bill.

‘However, web maintenance is just a part of the downtime, and the greater problem was changing the large reels that were in use for paper and OPP metallizing, especially changing reels often weighing greater than 3 or 4 tons some 3 to 4 meters in the air. This required cranes or specially designed handling equipment and added both to the complexity of there equipment in use, and the time taken.

            Aerre addressed this issue with their innovative design. All reels were handled at floor level reducing the need for highly specialised equipment, reducing operator fatigue, improving safety and reducing time.’

 

            I contrast this to the solution to this problem from GVE who went a different direction and produced a fully automated reel changing system that could remove the metallized roll and add a new uncoated roll.  This was used on the heaviest of paper metallizing systems with rolls of 4 tonnes or so.  

 

 

            The argument against these developments has always been cost and complexity. The trouble is that unless more systems with these features are built and the designs refined then it is very hard to reduce the complexity and cost.  A classic chicken and egg situation; where if the cost is not less then none will be bought but unless some are bought the costs cannot be reduced.   The cost benefits are much harder to assess as these are often very specific to the way customers operate their systems and will be affected by local costs.  Also over the years the frequency of web breaks looks to have reduced. I do not know if this is due to improvements in web quality or improved winding control or both.  Whatever the reason, the reduced frequency means that the benefits of having a reduced downtime after these events becomes of less importance.  Similarly with boat lifetimes being extended the number of boat exchanges per year is reduced and so the benefit of the faster source exchange is reduced. With these benefit reductions the cost justification becomes harder to achieve unless the system cost is similarly reduced.  

            Those who lose out are the operators. Their work remains the same rather than becoming easier.  Replenishing wire feeds, boats and cleaning feed tubes, etc, will remain a high pressure operation as it is all compressed into the time between deposition cycles. Operators working under pressure are prone to mistakes. Taking time to properly seat boats, clean and check wire feeds are fully and easily working can have production advantages. 

            As it is the margins on metallized products often means that the systems bought are chosen on minimum cost alone.  This again compounds the problem of making design advances as the only developments of interest appear to be those that reduce costs.  

 

 

Finally a comment from Bill that suitably summarises current systems design.

‘There has been no shortage of innovation in chamber design over the years, but it is still a surprise to me that in many instances, the designs of today do not ease the operator workloads, and areas such as reel changing, source maintenance, and chamber access is still as problematical as they were many years ago.’ 

 

 

 

 

 

December 19, 2008

Adhesion problems

I get many questions sent in of which a fair proportion relate to problems of adhesion.  These can be largely divided into two problems. The immediate problem of lack of adhesion during metallization is one problem. The second problem is the delamination of the coating sometime after metallization.

It is always worth investigating the surface energy of the substrate with the intention of maximising the surface energy to improve the nucleation and adhesion.  Any surface treatment will clean the surface as well as increasing the surface energy.  This can also be part of the solution to the problem of post deposition delamination.

What helps in solving adhesion problems is collecting information. This should start with any information that arrives with the incoming material.  It should also include details of time, temperature and humidity.  It is surprising how many of the adhesion problems relate to climate changes.  If the substrate has been corona treated it is often set up in one season but then is used in all seasons. Changes in humidity will affect the corona treatment as the water vapour changes the plasma performance.  Also, after deposition, high moisture levels can end up with moisture appearing at interfaces where it can cause swelling and delamination.  This takes time and so may not appear as a problem until weeks after the metallization.

Thus my advice would always be to continuously record the temperature and humidity as well as film storage times so that any adhesion problems might be correlated against the atmospheric conditions. 

December 17, 2008

Sustainability Webinar SCHEDULE

Full details of the series of webinars on the topic of Sustainability that are being run

 by AIMCAL.  These events are free but with limited numbers of attendees places available.

For details of registering go to www.aimcal.org

 

 

Sustainability Webinar SCHEDULE

January 8, 2009, 2:00 Eastern
Packaging and the Environment: Debunking the Myths


Kenneth Marsh,  Kenneth S. Marsh & Associates, Ltd.
Abstract:

Packaging is often perceived as the filler of landfills, cause for litter, and an item that retailers
love to force onto consumers in volume far beyond requirements. None of these statements is
true, but a typical consumer does not notice packaging materials until they are discarded.
“Packaging and the Environment: Debunking the Myths” will demonstrate how packaging is a
key to economic development, necessity for health, and even reduces municipal solid waste.
You will leave this session with a clearer perspective on the impact of packaging in the US and
around the world.


January 13, 2009, 2:00 Eastern
Sustainability - Unraveling the Mystery


Jeff Wooster, Dow Chemical Company
Abstract:


Sustainability has grown tremendously in importance both to the packaging
industry and society in general. This paper will present an overview and
help the audience understand the big picture view of sustainability
including limitations of current approaches and the importance of balancing
trade-offs for maximum environmental, social, and economic benefit.


January 22, 2009, 2:00 Eastern
Meeting Sustainability Initiatives Without Compromising Performance or Increasing Cost
Click HERE to register for this free webinar!


Dante Ferrari , Celplast Metallized Products
Abstract:


This presentation provides a review of how the sustainable packaging initiative has steered the
efforts of many companies in the flexible packaging industry. We will also review how the sustainability initiative has directed us to develop products that are made from renewable
resources, but do not compromise the functionality required in flexible packaging. Layer
elimination and down-gauging have typically been associated with cost savings programs. During
this discussion we will also show how sustainability has stimulated these initiatives and the performance products that have come as a result.

Click here for the bio


January 29, 2009, 2:00 Eastern
Increasing Energy Efficiency in the Web Coating Process


Dan Bemi,  MEGTEC Systems
Dr. Ed Cohen, Edward D Cohen Consulting
Abstract:


The Web Coating & Laminating process is very dependent on fossil fuels, petroleum, coal and gas as a source of energy for the numerous process functions, coating, drying, web transport, slitting chopping, lamination, heating buildings etc. Historically, there has been virtually unlimited availability of fossil fuels at reasonable price. As a result, energy costs were minimal and there was little concern about adequate supply.

However, in recent years, the costs for fossil fuels have significantly escalated as shown in Table 1 and current prices are $110-120 /barrel for crude oil.

Table 1
Year Nominal $/Barrell Inflation Adjusted 2007
2002 $22.81 $26.61
2003 $27.69 $31.62
2004 $37.66 $41.84
2005 $50.04 $53.77
2006 $58.30 $60.73
2007 $64.20 $64.92

In addition, rapid growth in China and India has increased demand and the rate of development of new oil is not matching current consumption. In other words, fossil fuel based energy costs will continue to escalate.

In order to remain competitive in this climate of rising energy costs, converters must start focusing on reducing energy consumption, modifying processes to be more efficient, and utilizing renewable resources in production plants. This paper will attempt to identify the major energy users in the coating and laminating processes along with some of the methods used to reduce process energy consumption without sacrificing product quality, process safety or environmental stewardship.  

Some of the technical topics to be discussed are as follows:

• Basic comparison of energy usage in various coating processes, water-based, solvent-based, solventless, extrusion and hot melt coating etc.
• Proven methods for optimizing the energy efficiency of existing and new drying systems.
• Modifying coating formulations to reduce energy consumption.
• Plant and process energy recovery and recycling opportunities.
• Alternate energy sources 


February 5, 2009, 2:00 Eastern
Dwindling Resources - A Molehill out of a Mountain


Charles Bishop, CA Bishop Consutling
Abstract:


There has been plenty of publicity about the rapid increase in the price of
Indium. This price rise was as a result of a number of factors such as it
only being mined as a by-product of zinc and their being only limited
stockpiles. This was exacerbated by a large increase in its use for
transparent conducting coatings for the display industry as well as the
newer faster increase in the photovoltaic industry. The net result of this
was that companies suddenly found that recycling did make sense and so the
supply was enhanced, at least for a time, by the input of recovered indium.

Since that time if you have observed the metals trading markets you will have seen all kinds of price increases in materials that heretofore we have thought of as abundant. In reality with the increased world population and increasing affluence, the demand for goods is increasing and the amount of materials being tied up in these goods is increasing. This requires
mining more materials and, for some, this is becoming more difficult and
expensive as these materials are found to be increasingly scarce.

In this paper I will highlight some of the other materials that may be under threat and hence likely to continue to rise in price.

 

Webinars

AIMCAL are running a series of Webinars.  Some of these will be presentations of papers from the last Fall Conference that are thought to be of possible interest to a wider audience and to those who were not able to attend.  If you are interested in seeing the full list of Webinars go to www.aimcal.org and follow the instructions/options as you will see I shall be presenting the following topic as detailed below.


Join us for a Webinar on February 5

 
  Dwindling Resources - A Molehill Out of a Mountain


There has been plenty of publicity about the rapid increase in the price of Indium. This price rise was as a result of a number of factors such as it only being mined as a by-product of zinc and their being only limited stockpiles.  This was exacerbated by a large increase in its use for transparent conducting coatings for the display industry as well as the newer faster increase in the photovoltaic industry.  The net result of this was that companies suddenly found that recycling did make sense and so the supply was enhanced, at least for a time, by the input of recovered indium.  

Since that time if you have observed the metals trading markets you will have seen all kinds of price increases in materials that heretofore we have thought of as abundant.  In reality with the increased world population and increasing affluence, the demand for goods is increasing and the amount of materials being tied up in these goods is increasing. This requires mining more materials and, for some, this is becoming more difficult and expensive as these materials are found to be increasingly scarce.  

In this paper I will highlight some of the other materials that may be under threat and hence likely to continue to rise in price.

Title: Dwindling Resources - A Molehill Out of a Mountain

Date:Thursday, February 5, 2009

Time:2:00 PM - 3:00 AM EST


After registering you will receive a confirmation email containing information about joining the Webinar.

December 15, 2008

Solar cells – photovoltaics

Anyone reading the scientific press over the last year or so will have seen huge publicity given to the millions, if not billions, that are being spent on photovoltaics.  Much of the money is raised through venture capital but governments are also helping with things like buy-back tariffs that allow any excess electricity to be sold to the electricity companies at a financially attractive rate.

The result of all this money has its good points and bad points for the vacuum coating industry.  The vacuum system manufacturers are happy because most, if not all, have full order books.  This may not be as good for vacuum system buyers as this leads to longer lead times for system delivery and less requirement on the manufacturers to bargain over prices.

This delivery delay has also brought opportunities for companies who have not previously built roll-to-roll coaters to enter the market. I know of several who have seized this opportunity to promise an early delivery, compared to the established manufacturers, to secure an order.  This also has the perceived advantage of secrecy as some manufacturers have several orders and so potentially are building machines for customers who will be competitors.  This is no different to the established metallizing industry but within photovoltaics there is a level higher paranoia about intellectual property that obviously causes some purchasers ulcers in worrying if something, they think is proprietary, is going to be disclosed elsewhere.  Time will tell if these system manufacturers that have now built their first roll-to-roll coater will now start to offer metallizers and so offer more choice and possibly bring back pricing pressure.

It is not only the system manufacturers who are benefiting but also the other suppliers. This has the effect that it increases the lead time on some components which also has the potential to lengthen the build times as well as delaying repairs or maintenance.

When reading the press there are frequent claims for world record performance cell efficiency.  Often the reason for trying to get the ‘world record’ is to get the publicity to help get the venture capital funding.  However it is worth noting that often the sample that is tested may only be 10mm square and some also include layers such as an anti-reflecting surface to get every last bit of efficiency out of the sample. The samples may also be produced in static vacuum deposition systems and so it is probably not surprising that, in transferring the static process from the 10mm size to a dynamic wide roll-to-roll process, the efficiency takes a dive.  To recover the efficiency takes time, sometimes years and it is a race because competitors are doing exactly the same.  What is not included in the ‘world record’ efficiency test is anything to do with the lifetime of the cell.  Once the cell is produced it need to have contacts attached and then the whole thing needs to be protected.  Silicon solar cells have extended lifetimes from 15 years to 25 years and there has been talk in extending this further into 30+ years.  So for these newer designs of cells there is an expectation that they will have to have long lifetimes. This may not have to be as long as for silicon cells as the production costs are lower the payback time will be much shorter.  Even so the cells will have to be effectively protected by a barrier material. This presents a huge opportunity for some of the newer barrier materials that have a performance similar to those required by the display industry.  These are sometimes referred to as ultra barrier materials.  Several of these barrier materials have been promised but none are available in large quantities.  Most of these materials include some vacuum deposited layer and so this too can be expected to provide more orders for roll-to-roll vacuum coaters adding to the already full order books.  For those who are looking to produce ultra barrier type materials this additional high volume market just adds to the incentive to overcome the production difficulties in producing the necessary high quality barrier material.

There may be questions about whether the boom will last and the answer is yes although it will not be consistent.  Some solar companies will fail and this will put some second-hand machines onto the market. Just how many companies fail will depend on the demand for cells and the patience of the venture capital backers.  The market gurus claim that we are heading for a world over capacity of cells as all the different investments start producing material and that this will last for several years. Thus some of the predicted machine requirements may be delayed or cancelled. 

So despite the financial doom and gloom that is being written about elsewhere things are generally positive in vacuum deposition system building.        

December 12, 2008

Optimising plasma treatment

Hi, how can we optimise the effectiveness of plasma treatment in a vacuum process with a constant gas composition being of 80% Argon and 20% oxygen in one cylinder?

Answer

You have three process controls that can be varied, gas flow which gives the plasma pressure, power and web winding speed.  Assuming that your web winding speed is defined by the required coating thickness and aluminium deposition rate this only leaves the gas flow and power to control.

The then is to fix the gas flow and then to progressively increase the plasma power and evaluate the coating adhesion that is produced. This can then be repeated for different gas flows.  Probably the biggest problem is the evaluation of the results. Measuring adhesion cannot be done using the simple tape test because the tape test is so variable and does not give any real measurement of adhesion.  Using something like the tensile test where the amount of cracking is monitored which can be converted into a measure of interfacial adhesion.

A possible alternative is to do the plasma treatment and not deposit the aluminium onto the web. In this way the surface energy can be measured. The surface energy can be expected to increase with increasing power up to a point where the surface energy reaches a plateau.  It is important that the web is not over treated and the plasma treatment is done only to the point where the surface energy just reaches the maximum value.  Treating beyond this point only introduces additional surface damage that will then begin to make the adhesion fall from the maximum.

Note that the plasma treatment that you optimise will be for that particular substrate material and may no longer be optimised for other grades or the same nominal material but from other suppliers.  This is because other grades may not have the same surface as the one you are using for the optimisation trials.  This is just a warning to be careful about assuming that optimisation on one substrate will be good for every grade of material.  It may be, but if you find later that the adhesion is not as good for a different grade of material it may not be a problem of the plasma other than it is not optimised for that particular grade.

However I recognise that it is impractical to have to go through an optimisation test for every type of substrate and grade and so a reasonable action is to optimise the process for one polymer type and grade and then use the same process for all other films. It would be worth optimising the process again if the polymer type is changed as different polymers contain different additives.  If the optimisation ends up with the same plasma gas flow and power then it is more likely that the plasma treatment will be useful for most grades even if it is not optimised.

I hope this helps.

December 06, 2008

Pin-windows, pinholes, starry sky effect.

The root cause of the ‘starry sky’ effect, pinholes or pin-windows is that there is dust/debris on the web before it is metallized and then some time following metallization some of the dust/debris is moved leaving behind the small areas of unmetallized web, the pinholes you see as the ‘starry sky’ effect. 

 

            Corona treatment and other plasma treatments do not remove dust/debris.  It is commonly believed that plasmas can remove any electrostatic charge and the dust/debris will fall off the surface but this is not really true. It is only dust/debris that is very large, probably greater than 50 microns, that has the adhesion force dominated by electrostatic attraction that can be released by discharging using a plasma treatment.   Dust/debris is held on the surface by Van der Waals forces or pressed into the surface or stuck on the surface by residuals carrier in water vapour. This makes the dust/debris hard to remove.  This is why to remove this type of dust/debris it requires a physical technique such as a tacky roll to remove the dust/debris to reduce the size and amount of dust/debris on the surface and hence minimise the pinholes, pin-windows or the starry sky effect.

 

Changes to the number and size of pinholes can sometimes change and then if there have been minor changes to the process they may be linked to these changes.  This correlation is often not real but is simply coincidental.  For example changing the corona treatment is unlikely to affect the amount of dust/debris on the surface as little or no dust/debris will be removed by discharging any electrostatic charge and the plasma will not etch off the dust/debris selectively.  The corona can improve the adhesion which may resist better some sliding of debris that would show up as scratching with a pinhole at the end of the scratching.

 

            Where there are differences between films it could simply be that the starting film is from a different batch and one has more debris on the surface than the other.  Alternatively if there are differences it is worth looking at is the whole winding process in particular the tension, number of front surface rolls and the contact area.   If there are differences in tension or front surface contact rolls and area then it is likely that the higher tension or greater amount of contact will produce more pinholes or stars in the starry sky effect.

 

 

December 03, 2008

Adhesion problems

I get many questions sent in of which a fair proportion relate to problems of adhesion.  These can be largely divided into two problems. The immediate problem of lack of adhesion during metallization is one problem. The second problem is the delamination of the coating sometime after metallization.

It is always worth investigating the surface energy of the substrate with the intention of maximising the surface energy to improve the nucleation and adhesion.  Any surface treatment will clean the surface as well as increasing the surface energy.  This can also be part of the solution to the problem of post deposition delamination.

What helps in solving adhesion problems is collecting information. This should start with any information that arrives with the incoming material.  It should also include details of time, temperature and humidity.  It is surprising how many of the adhesion problems relate to climate changes.  If the substrate has been corona treated it is often set up in one season but then is used in all seasons. Changes in humidity will affect the corona treatment as the water vapour changes the plasma performance.  Also after deposition high moisture levels can end up with moisture appearing at interfaces where it can cause swelling and delamination.  This takes time and so may not appear as a problem until weeks after the metallization.

Thus my advice would always be to continuously record the temperature and humidity as well as film storage times so that any adhesion problems might be correlated against the atmospheric conditions.  

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Contributing Authors

  • Adrian May
    Optima Control Solutions
  • David Roisum
    Dr. David Roisum of Finishing Technologies is a well-known authority on web handling and converting.
  • Eldridge Mount III
    EMMOUNT Technologies
  • Rick Spencer
    Alacritas Consultancy Ltd.,